喹乙醇的电化学行为研究

北京大学学报（自然科学版）

喹乙醇的电化学行为研究

张成志¹, 贺维军², 李南强²

¹四川乐山师范专科学校化学系，乐山，614004; ²北京大学化学与分子工程学院，北京，100871

收稿日期:1997-04-28 出版日期:1997-11-20 发布日期:1997-11-20

Studies on the Electrochemical Behaviors of the Olaquindox

ZHANG Chengzhi¹, HE Weijun², LI Nanqiang²

¹Department of Chemistry, Leshan Teacher's College, Sichuan, 614004; ²College of Chemistry and Molecular Engineering, Peking University, Beijing, 100871

Received:1997-04-28 Online:1997-11-20 Published:1997-11-20

摘要/Abstract

摘要： 研究了喹乙醇在醋酸盐和磷酸盐两种缓冲溶液中的电化学行为。在pH=7.0的磷酸盐缓冲溶液中，使用单扫示波极谱获得了灵敏的吸附波。其导数波的波高h_p2与c_ola在4×10^-8～2×10^-5mol/L范围内成正比关系，检测下限为1×10^-8mol/L。在汞电极表面，喹乙醇的吸附遵从Frumkin吸附等温式。测定出吸附系数β=9.1×10⁴，吸引因素ν=0.8。在pH=4.5的醋酸盐缓冲溶液中，可以获得3个吸附波。分别测定出了3个波的表面电极反应速率常数k_s1=2.1s^-1，k_s2=2.2s^-1，k_s3=1.8×10³s^-1。分别讨论了两种缓冲溶液中的电极反应机理。

关键词: 喹乙醇, 喹垩啉, 循环伏安法, 计时电量法, 单扫极谱

Abstract: The electrochemical behaviors of the olaquindox were studied in acetate and phosphate buffer solutions respectively. In the phosphate buffer solution, at pH=7.0, two sensitive adsorptive waves were obtained by single-sweep polarography. The second peak height (h_p2) of derivative wave is proportional to cola from 4×10^-8 to 2×10^-5mol/L. The detection limit is down to 1×10^-8mol/L. On the surface of mercury electrode, the adsorption of olaquindox obeys Frumkin isotherm. The adsorption coefficient β=9.1×10⁴ and the interaction factor v=0.8 were determined. In acetate buffer solution, at pH=4.5, three adsorptive waves can be obtained. The rate constants of the surface electrode reaction as k_s1=2.1s^-1，k_s2=2.2s^-1，k_s3=1.8×10³s^-1were determined. The mechanisms of electrode reactions were discussed in the two buffer solutions.

Key words: olaquindox, quinoxaline, cyclic voltammography, chronocoulometry, single-sweep polarography

中图分类号:

O657.14

张成志, 贺维军, 李南强. 喹乙醇的电化学行为研究[J]. 北京大学学报（自然科学版）.

ZHANG Chengzhi,HE Weijun,LI Nanqiang. Studies on the Electrochemical Behaviors of the Olaquindox[J]. Acta Scientiarum Naturalium Universitatis Pekinensis.

[1]	蒋欢, 王婷, 郑彤, 任艳粉, 倪晋仁. 水体中磺胺甲恶唑在BDD电极体系中的电化学氧化机理[J]. 北京大学学报自然科学版, 2019, 55(3): 482-488.
[2]	包晓玉, 朱志伟, 李南强. 铟-荧光镓极谱络合吸附波的研究[J]. 北京大学学报（自然科学版）, 2000, 36(2): 149-152.
[3]	拓宏桂, 李南强 . 钒(Ⅳ)-槲皮素极谱络合物吸附波的研究[J]. 北京大学学报（自然科学版）, 1996, 32(2): 168-171.
[4]	拓宏桂, 贺维军, 李南强 . 钛(Ⅳ)-槲皮素-氯酸盐体系极谱催化波的研究[J]. 北京大学学报（自然科学版）, 1996, 32(2): 163-167.
[5]	乔庆东,高小霞. 叶绿素的电化学行为研究 Ⅱ去镁叶绿素和铜－叶绿素的伏安行为研究[J]. 北京大学学报（自然科学版）, 1995, 31(2): 205-211.
[6]	张成志,李南强. 锑(Ⅲ)－芦丁极谱络合吸附波的研究[J]. 北京大学学报（自然科学版）, 1995, 31(2): 192-197.