北京大学学报(自然科学版)

• 北京大学学报 •

在线大气汞分析仪在外场观测的应用及问题讨论---以无锡冬季观测为例

陈枳君1,2,张寅崧1,曾立民1,魏永杰1,唐孝炎1   

  1. 1. 北京大学环境科学与工程学院, 环境模拟与污染控制国家重点实验室, 北京100871; 2. 交通运输部水运科学研究院, 北京 100088;
  • 收稿日期:2011-05-14 出版日期:2012-07-20 发布日期:2012-07-20

Application and Problem Discussion of On-line Atmospheric Mercury Analyzer in Field Measurement: Take Measurement in Wuxi in Winter for Example

CHEN Zhijun1,2, ZHANG Yinsong1, ZENG Limin1, WEI Yongjie1, TANG Xiaoyan1   

  1. 1. College of Environmental Science and Engineering, Peking University, State key Joint Laboratory of Environment Simulation and Pollution Control, Beijing, 100871; 2. China Waterborne Transport Research Institute, Beijing 100088;
  • Received:2011-05-14 Online:2012-07-20 Published:2012-07-20

摘要: 利用实验组自主研发的在线大气汞分析仪, 于2010年12月30日至2011年1月14日在无锡市曹张子站(E120°17′40″, N31°33′36″)对大气气态总汞(TGM)进行了连续监测。观测期间, 汞分析仪运行稳定, 测得无锡市TGM浓度范围为2.33~66.85 ng/m3, 平均值为7.37 ng/m3。观测中发现在线大气汞分析仪能够对环境大气中汞之外的其他物质产生信号响应。推测该物质为与汞同源排放于大气中的锌, 实验室加标实验及观测数据为该推测提供了正面支持。这一发现为日后仪器的改进提供了思路, 经进一步的证实和条件优化后有望实现在线大气汞分析仪同时监测大气中汞的特殊来源(金属冶炼)。

关键词: TGM, 汞分析仪, 锌, 无锡

Abstract: During Dec. 30, 2010 to Jan. 14, 2011, measurement of total gaseous mercury (TGM) concentrations was carried out by using a set of online atmospheric mercury analyzer developed by Zeng’s group at Caozhang station (E120°17′40″, N31°33′36″) in Wuxi, and the analyzer performanced well. The mean concentration over the sampling period was 7.37 ng/m3 with a range from 2.33 to 66.85 ng/m3. Some other elements in the ambient air could also be detected by the analyzer. Zinc which was probably released during metal smelting with mercury could be the reason, and this was provided by data analysis and lab experiment. It provides a way for promotion of the analyzer and makes the analyzer monitoring the particular source (smelting) of TGM possible after some improve-ments.

Key words: total gaseous mercury, mercury analyzer, zinc, Wuxi

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