北京大学学报(自然科学版)

基于新型正极材料的高功率锂离子电池

王剑1), 李林香1), 其鲁2),3), 安平1)
(1)中信国安盟固利新能源科技有限公司, 北京, 102200; 2)北京大学化学与分子工程学院应用化学系新能源材料与技术实验室,北京, 100871; 3)通讯作者, E-mail: qilu@pku.edu.cn)   

  • 收稿日期:2006-09-18 出版日期:2006-12-30 发布日期:2006-12-30

High Power Li-ion Secondary Batteries Based on New Cathode Materials

WANG Jian1), LI Linxiang1), Qilu2, 3), AN Ping1)
(1)CITIC Guoan Mengguli New Energy Technology Co., Ltd., Beijing,102200; 2) New Energy Materials and Technology Laboratory, Department   

  • Received:2006-09-18 Online:2006-12-30 Published:2006-12-30

摘要: 采用尖晶石LiMn2O4材料制作了18650型锂离子电池, 分析了影响锂离子电池大电流放电性能的主要因素如极耳、极片、电解质溶液等。又采用新型正极材料LiMnxNiyCozO2开发出性能更优越的18650型高功率锂离子电池, 该电池可10C连续放电和8C快速充电, 并具有优秀的循环性能和搁置性能。18650型高功率锂离子电池的开发, 为研制混合电动车(HEV)用高功率锂离子电池提供了实验依据。

关键词: 锂离子二次电池, 高功率, 18650型, 电化学性能

Abstract: The 18650 lithium-ion secondary battery is prepared with spinel LiMn2O4 cathode material, and major factors affecting lithium-ion secondary battery's discharge performance under big currents are analyzed, including tab, electrode and electrolyte. Another 18650 high power lithium-ion secondary battery is prepared with innovative cathode material LiMnxNiyCozO2, which presents superior performance. The battery endures continuous discharge under 10C and quick charge under 8C and presents excellent cycling and storage performance. The development of 18650 high power lithium-ion secondary battery provides the experimental references for high power lithium-ion secondary battery for hybrid electric vehicle (HEV).

Key words: lithium-ion secondary battery, high power, electrochemical performance

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