驱油用部分水解聚丙烯酰胺微观性能评价方法研究

北京大学学报（自然科学版）

驱油用部分水解聚丙烯酰胺微观性能评价方法研究

廖广志^1,2,马季铭¹, 孙刚²,牛金刚^2,4,周吉生³,刘凤歧³

¹北京大学化学与分子工程学院，北京，100871；²大庆油田有限责任公司勘探开发研究院，大庆，163712；³吉林大学化学学院，长春，130023；⁴中国科学院兰州化学物理研究所，兰州，730000

收稿日期:2003-02-27 出版日期:2003-11-20 发布日期:2003-11-20

Studies on the General Performance of Partial Hydrolyzed Polyacrylamide Used in Oil Flooding

LIAO Guangzhi^{1, 2}, MA Jiming¹，SUN Gang², NIU Jingang^2,4, ZHOU Jisheng³, LIU Fengqi³

¹College of Chemistry, Peking University, Beijing, 100871; ²Development and Research Institute of Daqing Oil Field, Daqing, 163712; ³College of Chemistry, Jilin University, Changchun, 130023; ⁴Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou, 730000

Received:2003-02-27 Online:2003-11-20 Published:2003-11-20

摘要/Abstract

摘要： 利用多角激光光散射法测定了部分水解聚丙烯酰胺（HPAM）的重均分子量、根均方旋转半径、第二维里系数等微观结构性能参数，发现了常规聚合物微观结构性能参数与粘均分子量的联系，同时比较了超高分子量抗盐聚合物与常规聚合物微观结构性能参数的差异，指出粘均分子量等指标表征聚合物性能的误差和局限性，建议在现有评价方法中补充微观结构性能参数，以准确衡量HPAM的综合性能，优选高效聚合物品种，进一步提高聚合物驱的技术经济效果。

关键词: 部分水解聚丙烯酰胺, 超高分子量抗盐聚合物, 重均分子量, 根均方旋转半径, 第二维里系数, 特性粘数, 光散射

Abstract: The weight-average molecular weight (M_w)，root mean square radius (RMS) and second viral coefficient(A₂) of hydrolyzed polyacrylamide (HPAM) were investigated by a static laser light scattering. The results show that there is a relation between M_wand M_η (viscosity-average molecular weight) of HPAM and also point out the difference between ultra-high M_ηsalt-resistant HPAM and conventional HPAM by comparing the micro-performance. All of these show that the limits and errors in the characterization method of HPAM which is still used in some oilfields now. The suggestion is to add some micro-parameters in the characterization methods, so that an effective way can be elected to evaluate the general performances of HPAM correctly and to select more effective polymers which can improve technological and economical effects on Polymer Flooding.

Key words: hydrolyzed polyacrylamide, ultra-high M_ηsalt-resistant HPAM, weight-average molecular weight(M_w), root mean square radius(RMS), second viral coefficient(A₂), intrinsic viscosity, light scattering

中图分类号:

O631

廖广志,马季铭, 孙刚,牛金刚,周吉生,刘凤歧. 驱油用部分水解聚丙烯酰胺微观性能评价方法研究[J]. 北京大学学报（自然科学版）.

LIAO Guangzhi,MA Jiming,SUN Gang,NIU Jingang,ZHOU Jisheng,LIU Fengqi. Studies on the General Performance of Partial Hydrolyzed Polyacrylamide Used in Oil Flooding[J]. Acta Scientiarum Naturalium Universitatis Pekinensis.

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https://xbna.pku.edu.cn/CN/Y2003/V39/I6/815