摘要: CS2在Cu-S键中插入产物(Ph3P)2Cu(S2CSR)(R=But或C6H2Pri3-2, 4, 6)与CH2I2-丙酮-Py混合溶剂反应,获得了双核铜化合物[CuI(PPh3)(Py)]2和[CH2(C5H5N)2]2Cu2I6]
两个化合物晶体,用X射线单晶衍射法测得它们的晶体结构。
中图分类号:
汤卡罗,夏天兵,金祥林,唐有祺. CS2在Cu─S键中插入产物(Ph3P)2Cu(S2CSR)与溶剂反应的研究 Ⅲ
双核铜化合物[CuI(PPh3)(Py)]2和[CH2(C5H5N)2]2Cu2I6]的形成和晶体结构[J]. 北京大学学报(自然科学版).
TANG Kaluo,XIA Tianbing,JIN Xianglin,TANG Youqi. Study on the Reactions of Mononuclear Copper Complexes Formed by Insertion of CS2 into Cu-S Bonds with Various Solvents Ⅲ
Formation and Crystal Structure of [CuI(PPh3)(Py)]2 and [CH2(C5H5