在二甲亚砜溶剂中氯化钼氧卟啉和超氧自由基反应动力学研究Ⅰ反应中间物和反应动力学

北京大学学报（自然科学版）

在二甲亚砜溶剂中氯化钼氧卟啉和超氧自由基反应动力学研究
Ⅰ反应中间物和反应动力学

崔晓丽,黄维,杨惠星,高盘良,韩德刚

北京大学化学系，北京，100871

收稿日期:1995-03-31 出版日期:1995-11-20 发布日期:1995-11-20

Kinetic Studies of Reaction of Oxomolybdenum Tetraphonylporphrin Complex MoO(TPP)Cl with O^-₂ in the Presence of DMSO
(I) Intermediates and Kinetics

CUI Xiaoli, HUANG Wei, YANG Huixing, GAO Panliang, HAN Degang

Department of Chemistry, Peking University, Beijing, 100871

Received:1995-03-31 Online:1995-11-20 Published:1995-11-20

摘要/Abstract

摘要： 本文应用紫外－可见吸收光谱研究了高浓度二甲亚砜存在条件下，MoO(TPP)Cl与超氧自由基O^-₂的反应。通过研究确定了一系列反应中间物和反应产物，本文还报导了有关反应动力学数据和结果。

关键词: 氯化钼氧卟啉, 超氧自由基, 反应中间物, 反应动力学

Abstract: The kinetics of the reaction of MoO(TPP)Cl with superoxide anion radical O^-₂ in high concentration of DMSO has been studied, and a series ofintermediates were investigated. The kinetics results were discussed and the kinetic data raported.

Key words: oxomolybdenum tetraphenylporphrin complex, superoxide anion radical, intermediates, reaction kinetics

中图分类号:

O643.1

崔晓丽,黄维,杨惠星,高盘良,韩德刚. 在二甲亚砜溶剂中氯化钼氧卟啉和超氧自由基反应动力学研究
Ⅰ反应中间物和反应动力学[J]. 北京大学学报（自然科学版）.

CUI Xiaoli,HUANG Wei,YANG Huixing,GAO Panliang,HAN Degang. Kinetic Studies of Reaction of Oxomolybdenum Tetraphonylporphrin Complex MoO(TPP)Cl with O^-₂ in the Presence of DMSO
(I) Intermediates and Kinetics[J]. Acta Scientiarum Naturalium Universitatis Pekinensis.

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https://xbna.pku.edu.cn/CN/Y1995/V31/I6/666