北京大学学报(自然科学版)

ZnCl2/分子筛型固体电解质的导电性能研究

杨华铨,张静芳,吴群,杨文治   

  1. 北京大学化学系,北京,100871
  • 收稿日期:1993-07-20 出版日期:1995-03-20 发布日期:1995-03-20

The Study on the Conductivity of ZnCl2/Molecular Sieve Solid Electrolytes

YANG Huaquan, ZHANG Jingfang, WU Qun, YANG Wenzhi   

  1. Department of Chemistry, Peking University, Beijing, 100871
  • Received:1993-07-20 Online:1995-03-20 Published:1995-03-20

摘要: 用交流阻抗方法研究ZnCl2/分子筛固体电解质(MSE)的导电性能。发现含水量与MSE的导电率密切相关。可以认为10%的含水量是MSE吸水饱和点。对MSE导电率随含水量变化及导电机理进行了讨论。

关键词: 分子筛, 固体电解质, 电导, 含水量, 阻抗

Abstract: The A C impedance method was used to studying the conductivity of ZnCl2/molecular sieve solid electrolytes(MSE). It was found that condutivity of MSE depends on it's water content. ~10% water content is the saturate point of absorptive water of MSE conceivably. The conductivity of MSE changes withit's water content and the mechanism of it's the conductivity were discussed.

Key words: molecular sieve solid electrolyte, conductivity, water content, impedance

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