Acta Scientiarum Naturalium Universitatis Pekinensis

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Studies on the Synthesis of Sesamin-Group Lignans VII. Selective Oxidation of 2-Arylfuran-3, 4-dicarbinol

CHEN Bingzi, CHENG Peng, PEI Weiwei, YE Xiulin   

  1. College of Chemistry and Molecular Engineering, Peking University, Beijing, 100871
  • Received:1997-04-02 Online:1997-11-20 Published:1997-11-20

芝麻素类型木脂素的合成研究(Ⅶ)2-芳基呋喃-3,4-二甲醇的选择性氧化

陈冰子,程鹏,裴伟伟,叶秀林   

  1. 北京大学化学和分子工程学院,北京,100871

Abstract: Tetrakis-pyridinocobalt (II)-dichromate [(HCrO4)2-Py4-Co(II)] was used for the selective oxidation of 2-arylfuran-3, 4-dicarbinol to 2-arylfuran-3- carbinol-4-carbinal in about 60% yields.

Key words: 2-arylfuran-3, 4-dicarbinol, 2-arylfuran-3-carbinol-4-carbinal, 2-arylfuran-3, 4-dicarbinal

摘要: 氧化剂四吡啶重铬酸钴络合物用于把2-芳基呋喃-3,4-二甲醇选择性地氧化成2-芳基呋喃-3-甲醇-4-甲醛,产率约为60%。

关键词: 2-芳基呋喃-3, 4-二甲醇, 2-芳基呋喃-3-甲醇-4-甲醛, 2-芳基-呋喃-3, 4-二甲醛

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