Acta Scientiarum Naturalium Universitatis Pekinensis

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Research on the Anti-Diffusion Behavior of ZnO/Polyurethane Coatings

YANG Lihong1, 4), LIU Fuchun2), ZHANG Zhiqiang3), HE Ping1), HAN Enhou2), Qilu1)
(1) New Energy Materials and Technology,Department of Applied Chemistry, College of Chemistr   

  • Received:2006-09-18 Online:2006-12-30 Published:2006-12-30

氧化锌改性聚氨酯涂层的抗介质扩散行为研究

杨立红1, 4), 刘福春2), 张志强3), 何平1), 韩恩厚2), 其鲁1)
(1)北京大学化学与分子工程学院, 应用化学系, 新能源材料与技术实验室, 北京, 100871; 2)中国科学院金属研究所, 环境腐蚀中心, 沈阳, 110016; 3)中国石油青海油田公司多元开发处, 敦煌, 73   

Abstract: The anti-diffusion of ZnO/polyurethane coatings were studied by using the impedance spectroscopy technique. Results indicate that the coating with P/B=1 has the best anti-diffusion and salt spray performance, the breakpoint frequency of the coating with P/B=1 is lower than others, which indicates the smaller defect area.

Key words: EIS, salt-spray test, anti-diffusion, ZnO/polyurethane coating

摘要: 研究了添加不同颜基比(P/B)ZnO的聚氨酯涂料在3.5%氯化钠溶液中的电化学阻抗谱特征, 结果表明, 添加量为P/B=1的涂层, 颜料分布均匀适中, 具有最佳抗介质渗透性能, 耐盐雾性能较好, 且该涂层特征频率较低, 表明其具有最小的涂层缺陷面积。

关键词: 电化学阻抗谱, 盐雾测试, 抗扩散, ZnO改性聚氨酯涂料

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