Acta Scientiarum Naturalium Universitatis Pekinensis

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The Study on the Rearrangement Reaction with Loss of Alcohol of Cyclopentene-one-carboxylic Esters under EI-MS

YU Zhenpei, LIN Xiaoyuan, HE Xiaoran, ZHU Yiqiang   

  1. College of Chemistry and Molecular Engineering, Peking University, Beijing, 100871
  • Received:1996-09-26 Online:1997-03-20 Published:1997-03-20


俞振培, 林孝元, 贺晓然, 朱轶强   

  1. 北京大学化学与分子工程学院,北京,100871

Abstract: Hydrogen atom is transferred from an methylene activated by the neighboring group effect to the saturated oxygen of the ester group and then results in rearrangement reaction with the loss of alcohol.

Key words: active methylene group, rearrangement, loss of alcohol

关键词: 活泼亚甲基, 重排, 失醇

CLC Number: