Acta Scientiarum Naturalium Universitatis Pekinensis

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Kinetic Studies of Reaction of Oxomolybdenum Tetraphonylporphrin Complex MoO(TPP)Cl with O-2 in the Presence of DMSO
(I) Intermediates and Kinetics

CUI Xiaoli, HUANG Wei, YANG Huixing, GAO Panliang, HAN Degang   

  1. Department of Chemistry, Peking University, Beijing, 100871
  • Received:1995-03-31 Online:1995-11-20 Published:1995-11-20

在二甲亚砜溶剂中氯化钼氧卟啉和超氧自由基反应动力学研究
Ⅰ反应中间物和反应动力学

崔晓丽,黄维,杨惠星,高盘良,韩德刚   

  1. 北京大学化学系，北京，100871

Abstract: The kinetics of the reaction of MoO(TPP)Cl with superoxide anion radical O-2 in high concentration of DMSO has been studied, and a series ofintermediates were investigated. The kinetics results were discussed and the kinetic data raported.

Key words: oxomolybdenum tetraphenylporphrin complex, superoxide anion radical, intermediates, reaction kinetics

摘要： 本文应用紫外－可见吸收光谱研究了高浓度二甲亚砜存在条件下，MoO(TPP)Cl与超氧自由基O-2的反应。通过研究确定了一系列反应中间物和反应产物，本文还报导了有关反应动力学数据和结果。

关键词: 氯化钼氧卟啉, 超氧自由基, 反应中间物, 反应动力学

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