Synthesis and Crystal Structure of Sc(III) Complex of 1-Phenyl-3-Methyl-4-Benzoyl-Pyrazolone-5

Acta Scientiarum Naturalium Universitatis Pekinensis

Previous Articles Next Articles

Synthesis and Crystal Structure of Sc(III) Complex of 1-Phenyl-3-Methyl-4-Benzoyl-Pyrazolone-5

ZHANG Yi¹，LI Biaoguo¹，JIN Tianzhu¹，HUANG Chunhui¹，XU Guangxian¹，HAN Yuzhen²，LI Genpei²

¹Research Centre of Rare Earth Chemistry, Peking University, Beijing, 100871; ²Institute of Physical Chemistry, Peking University, Beijing, 100871

Received:1993-08-10 Online:1995-07-20 Published:1995-07-20

钪与1－苯基－3－甲基－4－苯甲酰吡唑啉酮－5配合物Sc(PMBP)₃的合成及晶体结构

张毅¹,李标国¹,金天柱¹,黄春辉¹,徐光宪¹,韩玉真²,李根培²

¹北京大学稀土化学研究中心, 北京，100871；²北京大学物理化学研究所，北京，100871

Abstract

Abstract: The complex Sc(PMBP)₃ has been synthsized, where HPMBP= 1-phenyl-3-methyl-4-benzoyl-pyrazolone-5. Its crystal structure has been determined with a four-circle X-ray diffractometer. The crystal is triclinic with space group P1. The cell parameters are as follows: a=3.090(2)nm, b=1.2034(6)nm, c=1.2025(6)nm, α=86.64(4), β=81.13(5), γ=81.11(5)°, V=4.362(4)nm³, Z=4. In the crystal Sc(III)ion is coordinated by six oxygen atoms from three PMBP molecules, so that the coordination number of Sc(III)is six, froming an octahedron.

Key words: 1-phenyl-3-methyl-4-benzoyl-pyrazolone-5, scandium complex, crystal structure

摘要： 用Ｘ射线衍射方法测定了所合成标题配合物的晶体结构。晶体属三斜晶系，Ｐ1空间群。晶胞参数：a=3.090(2)nm, b=1.2034(6)nm, c=1.2025(6)nm；α=86.64(4)，β=81.13(5), γ=81.11(5)°；Ｚ＝４。配合物中钪（Ⅲ）配位多面体为八面体。

关键词: 钪配合物, 1－苯基－3－甲基－4－苯甲酰吡唑啉酮－5, 晶体结构

CLC Number:

O766

ZHANG Yi,LI Biaoguo,JIN Tianzhu,HUANG Chunhui,XU Guangxian,HAN Yuzhen,LI Genpei. Synthesis and Crystal Structure of Sc(III) Complex of 1-Phenyl-3-Methyl-4-Benzoyl-Pyrazolone-5[J]. Acta Scientiarum Naturalium Universitatis Pekinensis.

张毅,李标国,金天柱,黄春辉,徐光宪,韩玉真,李根培. 钪与1－苯基－3－甲基－4－苯甲酰吡唑啉酮－5配合物Sc(PMBP)₃的合成及晶体结构[J]. 北京大学学报（自然科学版）.

Add to citation manager EndNote|Ris|BibTeX

URL: https://xbna.pku.edu.cn/EN/

https://xbna.pku.edu.cn/EN/Y1995/V31/I4/387

[1]	ZHAN Jia, QIN Shan, GAO Jing. Storage of Water in Inorganic Salt Hydrates and the Implications to Latent Heat in Phase Changes [J]. Acta Scientiarum Naturalium Universitatis Pekinensis, 2018, 54(1): 80-86.
[2]	WANG Hui,PEI Weiwei,ZHANG Shiwei,SUN Guobin. Synthesis and Crystal Structure of(R)-2-Hydroxymethyl-1-aza-4-thiaspiro［4.5］decane [J]. Acta Scientiarum Naturalium Universitatis Pekinensis, 2004, 40(6): 849-854.
[3]	LI Qi,LIU Guang,ZHANG Shiwei. Synthesis and Structure of Compound [C(NH₂)₃]₂{[MoO(H₂O)C₂O₄]₂(μ-O)₂}·2H₂O [J]. Acta Scientiarum Naturalium Universitatis Pekinensis, 2003, 39(2): 171-177.
[4]	LIANG Yuhe,ZHA Zheng,HUA Ziqian,LIANG Xue,XU Qian,LU Guangying. Comparison of Structures between Crystals of Bar-headed Goose Hemoglobin Grown in Space and Earth [J]. Acta Scientiarum Naturalium Universitatis Pekinensis, 2001, 37(4): 483-489.
[5]	YAN Bing,CHEN Zhida,WANG Shixi. A Novel Tetranulcear Iron Complex［Fe₄O₂(O₂CC₂H₅)₇(bipy)₇］PF₆·(H₂O)₂ (bipy=2, 2′-bipyride): Synthesis and Crystal Structure [J]. Acta Scientiarum Naturalium Universitatis Pekinensis, 2001, 37(2): 265-270.
[6]	KOU Huizhong,GAO Song,SUN Baiwang,MA Baoqing. Self-assembly of an Unprecedented Cynao-bridged One-dimensional 4f-3d Complex[Nd(DMF)₄(H₂O)₂Cr(CN)₆]·nH₂O} [J]. Acta Scientiarum Naturalium Universitatis Pekinensis, 2001, 37(2): 261-264.
[7]	XU Jiaxi,JIN Sheng. Synthesis and Crystal Structure of 5-(2-bromophenyl)-1, 3, 3a-triphenyl-3a, 4, 5, 11-tetrahydro-3H-1, 2, 4-triazolo[4, 3-d][1, 5]benzothiazepine [J]. Acta Scientiarum Naturalium Universitatis Pekinensis, 1998, 34(4): 442-446.
[8]	LI Junran,ZHOU Liping,JIN Tianzhu,YU Kaibei. Synthesis and Crystal Structure of a Heteronuclear Complex of Erbium-Yttrium with Glutamic Acid: [ErY(Glu)₂(H₂O)₈](ClO₄)₄•2.75H₂O [J]. Acta Scientiarum Naturalium Universitatis Pekinensis, 1997, 33(4): 420-426.
[9]	YANG Weichun,JIN Tianzhu,ZHANG Shiwei. Crystal Structure of L-Tyrosine Perchlorate [J]. Acta Scientiarum Naturalium Universitatis Pekinensis, 1996, 32(4): 413-416.
[10]	JIN Xianglin,TANG Kaluo,ZENG Hui,TANG Youqi. Research on the Sythesis of New Silver Cluster Complexes by the Insertion Reaction of CS₂ into Ag-S Bonds(Ⅳ) Formation and Crystal Structure of a Tetranuclear Silver Cluster Complex (Ph₃P)₄Ag₄Br₄ [J]. Acta Scientiarum Naturalium Universitatis Pekinensis, 1996, 32(2): 151-156.
[11]	WANG Kezhi,HUANG Chunhui,ZHOU Yongfen,XU Guangxian,ZHOU Qifeng,LIN Xiuyun. Thermal Behaviors and Crystal Structure of Hemicyanines [J]. Acta Scientiarum Naturalium Universitatis Pekinensis, 1996, 32(2): 146-150.
[12]	TANG Kaluo,XIA Tianbing,JIN Xianglin,TANG Youqi. Study on the Reactions of Mononuclear Copper Complexes Formed by Insertion of CS₂ into Cu-S Bonds with Various Solvents Ⅲ Formation and Crystal Structure of [CuI(PPh₃)(Py)]₂ and [CH₂(C₅H_{5[J]. Acta Scientiarum Naturalium Universitatis Pekinensis, 1995, 31(6): 695-702.}
[13]	WANG Qiming,CAO Zhengmin,QIN Shan. Studies on TEM of Valleriite, Laiyuan, Hebei Province, China [J]. Acta Scientiarum Naturalium Universitatis Pekinensis, 1995, 31(6): 726-731.
[14]	LI Biaoguo,ZHANG Yi,JIN Tianzhu,HUANG Chunhui,XU Guangxian,HAN Yuzhen,SHI Nicheng. Synthesis and Crystal Structure of Tetrabutyl Ammonium Hexaisothiocyanato Scandium [(C₄H₉)₄N]₃[Sc(NCS)₆] [J]. Acta Scientiarum Naturalium Universitatis Pekinensis, 1995, 31(4): 394-399.
[15]	JIN Qingri,WANG Xiaoqing,JIN Tianzhu,XU Guangxian,SHI Nicheng,MA Zhesheng. Studies on Synthesis and Crystal Structure of an Erbiun (III) Complex with Serine [J]. Acta Scientiarum Naturalium Universitatis Pekinensis, 1995, 31(2): 218-223.

Synthesis and Crystal Structure of Sc(III) Complex of 1-Phenyl-3-Methyl-4-Benzoyl-Pyrazolone-5

钪与1－苯基－3－甲基－4－苯甲酰吡唑啉酮－5配合物Sc(PMBP)₃的合成及晶体结构

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Synthesis and Crystal Structure of Sc(III) Complex of 1-Phenyl-3-Methyl-4-Benzoyl-Pyrazolone-5

钪与1－苯基－3－甲基－4－苯甲酰吡唑啉酮－5配合物Sc(PMBP)3的合成及晶体结构

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

钪与1－苯基－3－甲基－4－苯甲酰吡唑啉酮－5配合物Sc(PMBP)₃的合成及晶体结构