Study on the Reactions of Mononuclear Copper Complexes Formed by Insertion of CS2 into Cu-S Bonds with Various Solvents Ⅲ Formation and Crystal Structure of [CuI(PPh3)(Py)]2 and [CH2(C5H5</su

Acta Scientiarum Naturalium Universitatis Pekinensis

Study on the Reactions of Mononuclear Copper Complexes Formed by Insertion of CS₂ into Cu-S Bonds with Various Solvents Ⅲ
Formation and Crystal Structure of [CuI(PPh₃)(Py)]₂ and [CH₂(C₅H_{5

TANG Kaluo, XIA Tianbing, JIN Xianglin, TANG Youqi

Institute of Physical Chemistry, Peking University, Beijing, 100871

Received:1994-07-14

Online:1995-11-20

Published:1995-11-20

CS₂在Cu─S键中插入产物(Ph₃P)₂Cu(S₂CSR)与溶剂反应的研究 Ⅲ
双核铜化合物[CuI(PPh₃)(Py)]₂和[CH₂(C₅H₅N)₂]₂Cu₂I₆]的形成和晶体结构

汤卡罗,夏天兵,金祥林,唐有祺

北京大学物理化学研究所，北京，100871

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Abstract

Abstract: Mononuclear copper complexes with structures of (Ph₃P)₂Cu(S₂CSR), formed by insertion of CS₂ into Cu-S bonds, can react with a various solvents undergoing some nucleophilic reactions. The two title compounds(IV, V)were obtained from the reaction of starting material(R=Bu^t, C₆H₂Prⁱ₃-2, 4, 6) with CH₂I₂-acetone mixed-solvent in the presence of pyridine and then self-assemblyin the same solution. Crystal data for compound IV: space group C₂/c, a=26.112(6), b=14.499(3), c=11.357(2)Å, β=95.18(2)Å, V=4282(15)Å³, Dc=1.650g/cm³, Z=4, R=0.0334 for 2182 independent reflections. Crystal data for compound V: space group P2₁/n, a=11.389(4), b=11.698(5), c=13.227(7)Å, β=114.99(4)°, V=1597(13)Å³, Dc=2.563g/cm³, Z=4, R=0.0627 for 1891 independent reflection.

Key words: CS₂ insertion reaction, dinuclear copper complex, crystal structure

摘要： CS₂在Cu-S键中插入产物(Ph₃P)₂Cu(S₂CSR)(R＝Bu^t或C₆H₂Prⁱ₃-2, 4, 6)与CH₂I₂-丙酮-Py混合溶剂反应，获得了双核铜化合物[CuI(PPh₃)(Py)]₂和[CH₂(C₅H₅N)₂]₂Cu₂I₆] 两个化合物晶体，用Ｘ射线单晶衍射法测得它们的晶体结构。

关键词: CS₂插入反应, 双核铜配合物, 晶体结构

CLC Number:

O614.121

TANG Kaluo,XIA Tianbing,JIN Xianglin,TANG Youqi. Study on the Reactions of Mononuclear Copper Complexes Formed by Insertion of CS₂ into Cu-S Bonds with Various Solvents Ⅲ
Formation and Crystal Structure of [CuI(PPh₃)(Py)]₂ and [CH₂(C₅H₅

汤卡罗,夏天兵,金祥林,唐有祺. CS₂在Cu─S键中插入产物(Ph₃P)₂Cu(S₂CSR)与溶剂反应的研究 Ⅲ
双核铜化合物[CuI(PPh₃)(Py)]₂和[CH₂(C₅H₅N)₂]₂Cu₂I₆]的形成和晶体结构[J]. 北京大学学报（自然科学版）.

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CS₂在Cu─S键中插入产物(Ph₃P)₂Cu(S₂CSR)与溶剂反应的研究 Ⅲ
双核铜化合物[CuI(PPh₃)(Py)]₂和[CH₂(C₅H₅N)₂]₂Cu₂I₆]的形成和晶体结构

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