Abstract: Nine new compounds of (α-alkyl-3, 3-dimethyl-2-norboranemethyl)acetate with alkyls as methyl, ethyl, n-propyl, isopropyl, n-butyl, isobutyl, sec-butyl, n-pentyl, isopentyl have been synthesized from camphene through a series of reaction of epoxidation, rearrangement, Grignard reagent addition and esterification etc. These compounds have been identified by GC, MS, IR and NMR.

Key words: (α-alkyl-3, 3-dimethyl-2-norboranemethyl) acetate, camphene, epoxidation, rearrangement, Grignard reaction, esterification

摘要： 以莰烯为原料，经环氧化等一系列反应得到乙酸（α-烷基-３-３-二甲基-２-降冰片烷甲基）酯（烷基为Me, Et, n-Pr, i-Pr, n-Bu, i-Bu, s-Bu, n-Am, i-Am）共9个新化合物，通过波谱及色谱确定了它们的结构及含量。

关键词: 乙酸（α-烷基-3-3-二甲基-2-降冰片烷甲基）酯, 莰烯, 环氧化反应, 重排反应, 酯化反应