Acta Scientiarum Naturalium Universitatis Pekinensis

Previous Articles     Next Articles

Study on the Polarographic Adsorptive Complex Wave of Antimony(III)-Rutin

ZHANG Chenzhi, LI Nanqiang   

  1. Department of Chemistry, Peking University, Beijing, 100871
  • Received:1993-08-26 Online:1995-03-20 Published:1995-03-20

锑(Ⅲ)-芦丁极谱络合吸附波的研究

张成志,李南强   

  1. 北京大学化学系,北京,100871

Abstract: In the buffer solution of 0.2mol/L HAc-NaAc, at pH 4.5, a sensitive adsorptive complex wave of Sb(III)-rutin can be obtained by using single-sweep polarography. The detection limitis down to 2.0×10-9 mol/L. The mechanism of electrode processeswere studied in detail.

Key words: antimony, rutin, single-sweep polarography

摘要: 在pH4.5的HAc-NaAc底液中,用单扫极谱法可得到Sb(Ⅲ)-芦丁灵敏的络合吸附波。csb在4.0×10-9~5.0×10-6mol/L范围内与其二阶导数波峰高有正比关系,检测限达2.0×10-9mol/L。对络合物的吸附机理和组成进行了研究,测定了有关电极反应的动力学参数。

关键词: 锑, 芦丁, 单扫极谱

CLC Number: