Acta Scientiarum Naturalium Universitatis Pekinensis

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Research on the Sythesis of New Silver Cluster Complexes by the Insertion Reaction of CS2 into Ag-S Bonds(Ⅳ) Formation and Crystal Structure of a Tetranuclear Silver Cluster Complex (Ph3P)4Ag4Br4

JIN Xianglin, TANG Kaluo, ZENG Hui, TANG Youqi   

  1. Institute of Physical Chemistry, Peking University, Beijing, 100871
  • Received:1995-04-25 Online:1996-03-20 Published:1996-03-20

应用CS在Ag-S键中的插入反应生成新型Ag原子簇化合物的研究
Ⅳ 四核银簇合物(Ph3P)4Ag4Br4的形成与晶体结构

金祥林, 汤卡罗, 曾辉, 唐有祺   

  1. 北京大学物理化学研究所,北京,100871

Abstract: The title complex was prepared through the reaction of (Ph3P)2Ag(S2CSR) (R=C6H5 or C6H2Pri3-2,4,6) formed by inserting of CS2 into Ag-S bond of AgSR in the presence of Ph3P with BrCH2CH2Br—P under mild conditions. The colorless block crystal belongs to rhombohedral system with the space group R3c, α=1.6421(2) nm, c=4.4075(9) nm, V=10.297(3) nm3, Dc=1.746 g·cm-3, Z=6. The final R is 0.033 for 2244 independent reflections. The four silver atoms and four bromine atoms form a distorted cube, and each silver atom is tetrahedral coordinated by one P and three Br atoms.

Key words: insertion reaction of CS2, silver cluster complex, crystal structure

摘要: 应用CS在AgS键中的单核插入产物(Ph3P)2Ag(S2CSR)(R=C6H5或 C6H2Pri3-2,4,6)与1,2-二溴乙烷-异丙醇混合溶剂反应,生成一个中性四核银簇合物(Ph3P)4Ag4Br4,并利用X射线单晶衍射法测定其晶体结构。

关键词: CS2插入反应, 四核银簇合物, 晶体结构

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